Magnetic Properties of FeCl_3-Graphite Compounds. : II. Magnetic Susceptibilities.

スポンサーリンク

概要

• 論文の詳細を見る

• Magnetic susceptibilities, χ, on the 1st and the 2nd stage FeCl_3-graphite compounds were measured in a temperature region between 1.5K and 77K. For both stage compounds, the temperature dependence of χ was explained as anisotropic 2-dimensional antiferromagnet. 4kThe anisotropy mainly results from the crystalline field and its consta with spin flopping in the basal plane. The 1st stage compound was the antiferromagnet with T_N=3.9K, J/k=-0.41K and effective anisotropy field ∣H_A∣=1.Oen Dt was estimated as +0.09cm^<-1>.For the 2nd stage compound, T_N=3.6K, J/k=-0.35K, ∣H_A∣=3.6kOe and D=+0.16cm^<-1> were obtained. The effect of the intercalation into graphite, which results in trigonal distortions of Cl octahedrons as well as size distributions of clusters, was found to be more important in the 2nd stage compound than in the 1st stage one. The interlayer interaction through graphite layer was negligible compared with H_A even in the 1st stage compound.

• 社団法人日本物理学会の論文
• 1974-04-15

著者

• Tsujikawa Ikuji

  Department Of Chemistry Faculty Of Science Kyoto University

• Tsujikawa Ikuji

  Department Of Chemisity Faculty Of Science Kyoto University

• Ohhashi Kentaro

  Department Of Chemistry Faculty Of Science Kyoto University

• TSUJIKAWA Ikuji

  Department of Chemistry, Faculty of Science, Kyoto University

関連論文

• Optical Investigations of Rare-Earth Orthochromites.III.GdCrO_3 and Summary of the R' Band in RCrO_3
• Magnetization of a Random Magnet, Ni_pMg_(1-p)(OH)_2
• High Field Magnetization of the One-Dimensional Ising Antiferromagnet CsCoCl_3・2H_2O
• Optical Spectrum of R'-Band in Spin Reorientated YbCrO_3 under High Magnetic Field
• Optical Absorption Spectrum in YbCrO_3 under High Magnetic Field
• Exciton Transfer in the Random Antiferromagnet CsMn_Co_xCl_3・2H_2O
• Exciton Transfer in the One-Dimensional Antiferromagnet CsCoCl_3・2H_2O
• Exciton-Magnon Transition in Linear Chain Compound CsCoCl_3・2H_2O
• Optical Investigations of Rare-Earth Orthochromites.II.RCrO_3(R=Er,Ho,Dy and Tb)
• Optical Investigations of YbCrO_3. III. : Cr^ Exciton- Yb^ Spin Flip Simultaneous Absorption
• Exciton Absorption Lines in Antiferromagnetic DyCrO_3
• Specific Heat of a Qusai-Two-Dimensional Antiferromagnet Ni (OH)_2
• Magnetic and Transport Properties of Ce-Ta-S Ternary System
• Optical Investigations of Rare-Earth Orthochromites.I.TmCrO_3
• Optical Investigations of YbCrO_3. II. : Metamagnertic Transition in YbCrO_3
• Optical Investigations of YbCrO_3. I. : Optical Absorption Spectra of Yb^ Ion
• Field-Induced Davydov Splitting of Excitons in Quasi-One-Dimensional Antiferromagat CsMnCl_3・2H_2O
• Photo-Induced Absorption Band in One-Dimensional Halogen-Bridged Mixed-Valence Platinum Complex:[Pt (en)_2][PtI_2(en)_2](SO_4)_2・6H_2O and its Au-Doped Complex:[Au_xPt_I (en)_2]SO_4・3H_2O
• Superconductivity in the Potassium Graphite Hydride C_8KH_
• Zeeman Effect of R Lines in TlCr-alum
• Paschen-Back Effect of R Lines in TlCr Alum
• Anisotropy of Zeeman Effects in Optical Absorption Spectra of Tetragonal Crystals Cs_3CoCl_5 and Cs_3CoBr_5. : I. Experimental Results
• Magnon Sideband of the ^4T_(^4D) State in the Quasi Two-Dimensional Antiferromagnet (C_2H_5NH_3)_2MnCl_4
• Temperature Dependence of the Absorption Spectra ^6A_→^4A_(^4G),^4E_g(^4G) in the Quasi Two-Dimensional Antiferromagnets (C_nH_NH_3)_2MnCl_4 (n=2,3)
• Zeeman Effect and Dilution Effect of Absorption Lines in GCrSH
• Dilution Splitting of R Lines of Cr^ in Ferroelectric GCrSH Crystals
• Magnetic Property of Quadri-Nuclear Cluster, [Cr{(OH)_2Cren_2}_3](SO_4)_3・10H_2O
• Magnetic Properties of FeCl_3-Graphite Compounds. : I. Mossbauer Studies
• Anisotropy of Zeeman Effects in Optical Absorption Spectra of Tetragonal Crystals Cs_3CoCl_5 and Cs_3CoBr_5. : II. Selection Rules and Analysis.
• Electrical Conductivity and Some Other Properties of the Partially Oxidized Salt of the Magnus Green Salt with the Formula Pt_6(NH_3)_Cl_(HSO_4)_4
• Responsible Layer for Superconductivity in the First Stage Potassium Graphite Intercalation Compound
• Physical Properties of a Quasi One-Dimensional Conductor Pt_6(NH_3)_Cl_(HSO_4)_4:Partially Oxidized Salt of the Magnus Green Salt
• Magnetic Properties of FeCl_2-Graphite Compounds. Mossbauer Effect and Magnetic Susceptibility Studies
• Phase Transition of a Random Magnet, Ni_pMg_(OH)_2
• Study of the Initial Tetragonal Distortion of the [CoX_4]^ Complex-Ion (X=Cl or Br) in Cs_3CoCl_5 and Cs_3CoBr_5 Crystals by the Effect of Uniaxial Stress on Optical Absorption-Lines. : I. Experimental Results
• The Pseudo Jahn-Teller Effect in the Excited State ^2E(^2D) of Tetragonal Crystals Cs_3CoCl_5 and Cs_3CoBr_5 Studied by the Effect of Uniaxial Stress and the Zeeman Effect on Absorption Spectra
• Magnetic Properties of FeCl_3-Graphite Compounds. : II. Magnetic Susceptibilities.
• Study of the Initial Tetragonal Distortion of the [CoX_4]_ Complex-Ion (X=Cl or Br) in Cs_3CoCl_5 and Cs_3CoBr_5 Crystals by the Effect of Uniaxial Stress on Optical Absorption-Lines. : II. Analysis and Estimation of the Jahn-Teller Coupling Constant
• Optical Activity Caused by Exciton Dispersion
• Anomalous Behaviour of an AC Susceptibility in a Random Magnet, Ni_pMG_(OH)_2
• Study of the Ground States ^4A_2 of Cs_3CoCl_5 and Cs_3CoBr_5 Crystals by the Zeeman Effect of Optical Absorption-Linses
• Magnetic Behaviours of a Random Magnet, Ni_pMg_(OH)_2
• The Optical Anisotropies and the Mechanism of Vibronic Transitions in Spectra ^4A_2→^2T_2(^2D) and ^2E(^2D) of Cs_3CoBr_5 and Cs_3CoCl_5 studied by the Effect of Uniaxial Stress and the Zeeman Effect
• Study of the Dependence of the Racah Parameter B on the Coordination-Bond Length in Cs_3CoCl_5 and Cs_3CoBr_5 Crystals by the Effect of Uniaxial Stress on Optical Absorption Spectra, and by Others
• Susceptibility Fluctuation in Superconducting First Stage Potassium Graphite Intercalation Compound near Transition Temperature
• Optical Activity of Iron Group Selenate Crystals. : I. Experimental Studies
• Zeeman Effect of Absorption Line of CsCr Alum
• Potassium Concentration Dependence of the Superconductivity in the Potassium Graphite Intercalation Compounds
• Magnetic Susceptibility of Tetrameric Co(II) Acetylacetonate
• Magnon Sideband in the Quasi Two-Dimensional Antiferromagnet (C_2H_5NH_3)_2MnCl_4
• タイトル無し
• Comparison between optical properties of sulfates and hydrogensulfates in halogen-bridged mixed-valence platinum(II, IV) complexes.
• A molybdenum polynuclear complex as small metallic particles.
• Magnetic properties of (.MU.-(ethylenediaminetetraacetato)-di-.MU.-sulfido-bis{oxomolybdate(V)})2- and (.MU.-(ethylenediaminetetraacetato)-di-.MU.-oxo-bis{oxomolybdate(V)})2- ions.
• Optical and ESR spectra for high-spin tetrahedral complexes of Co(III) and Co(II) in Keggin-structure heteropolytungstate.
• Study of mixed-valence state in halogen-bridged mixed-valence platinum(II,IV) complexes by temperature dependence of intervalence charge-transfer spectra.
• Synthesis and electrical conductivity of a new family of Pt mixed valence complexes : Pt6(NH3)14Cl10X4 (X=ClO4, BF4, and PF6).

もっと見る 閉じる

スポンサーリンク