Zeeman Effect and Dilution Effect of Absorption Lines in GCrSH
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概要
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Zeeman effect of the R and B lines in GCrSH was measured. No difference was observed between the Zeeman patterns of the R_1 and R_2 absorption lines. Non-zero g-values of the excited states were obtained from the patterns in a magnetic field perpendicular to the trigonal axis. From these results, it is concluded that these two lines are not attributed to the two transitions ^4A_2⇾E^^-(^2E) and ^4A_2⇾2A^^-(^2E) of a Cr^<3+> ion, but to the transition ^4A_2⇾E^^-(^2E) in the two different Cr^<3+> sites. Both the B_1 and the B_1' lines were assigned to ^4A_2⇾E^^-_b(^2T_2) from the Zeeman patterns in a high pulsed magnetic field. New lines were found in the R-line region when GCrSH was diluted by aluminum. They are considered to originate from certain kinds of Cr^<3> sites and to have relation with the ferroelectric character of the crystals. In the B-line region, however, no new lines were observed.
- 社団法人日本物理学会の論文
- 1971-02-05
著者
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Tsujikawa Ikuji
Department Of Chemisity Faculty Of Science Kyoto University
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Tsujikawa Ikuji
Department Of Chemistry Faculty Of Science Kyto Unviersity
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Ban Toshiro
Department Of Chemisity Faculty Of Science Kyoto University
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Ban Toshiro
Department Of Chemistry Faculty Of Science Kyto Unviersity
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Tamatani Masaaki
Department Of Chemistry Faculty Of Science Kyto Unviersity:(present Address) Horikawacho Works Tokyo
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