Reduction of Nitro and Nitroso Compounds with Tetracarbonylhydridoferrate

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概要

• 論文の詳細を見る

• An applicability of potassium tetracarbonylhydridoferrate as a reducing reagent to synthesis of primary amines from a wide variety of nitro and nitroso compounds has been examined. The reaction proceeds vigorously and exothermally at room temperature to give the corresponding amines in excellent yields. For nitroaryls, some substituents have interfering effect on the formation of amines. <I>o</I>-Nitrocinnamic aldehyde gives quinoline.

• 公益社団法人 日本化学会の論文

著者

• Mitsudo Take-aki

  Department Of Energy And Hydrocarbon Chemistry Graduate School Of Engineering Kyoto University

• Yamashita Masakazu

  Department Of Applied Chemistry Doshisha University

• Watanabe Yoshihisa

  Department Of Basic Geriatrics Graduate School Of Medical Science Kyoto Prefectural University Of Medicine

• Takegami Yoshinobu

  Department of Fuel Chemistry Faculty of Engineering Kyoto University

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