Liquid-phase Oxidation Catalyzed by Cu(II)–Cl System, I. Oxidation of Cyclohexene

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概要

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• Oxidation of cyclohexene catalyzed by Cu(II)–Cl systems was carried out in glacial acetic acid. The oxidation of cyclohexene with cupric chloride was highly accelerated by addition of various alkali chlorides. The decomposition of cyclohexenyl hydroperoxide, an intermediate product of the oxidation, was also accelerated by this catalyst system. Salts other than alkali chlorides had little effect. It was concluded that the activation of copper catalyst was due to the chloride ions which form a complex with copper. In the course of the reaction the catalyst loses its activity through ligand exchange with solvent molecule, acetic acid.

• 公益社団法人 日本化学会の論文

著者

• Takegami Yoshinobu

  Department of Fuel Chemistry Faculty of Engineering Kyoto University

• Imamura Sei-ichiro

  Department of Chemistry, Kyoto Institute of Technology

• Takegami Yoshinobu

  Department of Hydrocarbon Chemistry, Kyoto University

• Banba Toshiaki

  Department of Chemistry, Kyoto Institute of Technology

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