The reaction of disodium tetracarbonylferrate(-II) with aldehydes.

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概要

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• Disodium tetracarbonylferrate (–II) is an efficient catalyst for the dismutation of aromatic aldehydes to esters, 2RCHO→RCOOCH<SUB>2</SUB>R. Aliphatic ones give aldol-condensation products upon treatment with the ferrate. A successive reaction of the ferrate with an aldehyde, RCHO, and then with alkyl iodide, R'I, gives an ester, R'COOCH<SUB>2</SUB>R, after protonation. The mechanisms of these reactions are discussed.

• 公益社団法人 日本化学会の論文

著者

• Mitsudo Take-aki

  Department Of Energy And Hydrocarbon Chemistry Graduate School Of Engineering Kyoto University

• Yamashita Masakazu

  Department Of Applied Chemistry Doshisha University

• Watanabe Yoshihisa

  Department Of Basic Geriatrics Graduate School Of Medical Science Kyoto Prefectural University Of Medicine

• TAKEGAMI Yoshinobu

  Department of Hydrocarbon Chemistry, Faculty of Engineering, Kyoto University

• Takegami Yoshinobu

  Department of Fuel Chemistry Faculty of Engineering Kyoto University

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