Oxygen promoted addition of 1,3-dioxolane to electron-deficient alkenes.
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概要
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1,3-Dioxolane reacted with electron-deficient alkenes, such as diethyl maleate, maleic anhydride, diethyl fumarate and fumaronitrile, under an oxygen atmosphere or in air to give 1:1 adducts in good to excellent yields. The presence of oxygen promoted the reaction. The reaction appears to be characteristic of 1,3-dioxolane. Methylal and ethylal did not react with diethyl maleate under the same conditions.
- 公益社団法人 日本化学会の論文
著者
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Takeuchi Ryo
Department Of Applied Biological Science Faculty Of Science And Technology Tokyo University Of Scien
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Tsuji Yasushi
Department Of Energy And Hydrocarbon Chemistry Graduate School Of Engineering Kyoto University
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Watanabe Yoshihisa
Department Of Basic Geriatrics Graduate School Of Medical Science Kyoto Prefectural University Of Medicine
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