The Facile Syntheses of Aldehydes and Aldehydic Acids from Carboxylic Acid Anhydrides Using Disodium Tetracarbonylferrate (–II)

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概要

• 論文の詳細を見る

• Disodium tetracarbonylferrate reacts readily with aliphatic and aromatic carboxylic acid anhydrides under mild conditions; the corresponding aldehydes are formed in high yields by quenching the reaction solution with acetic acid. Intermolecular anhydrides give aldehydes and acids, and intramolecular ones give aldehydic acids. The reaction mechanism <I>via</I> acylcarbonylferrates is assumed.

• 公益社団法人 日本化学会の論文

著者

• Mitsudo Take-aki

  Department Of Energy And Hydrocarbon Chemistry Graduate School Of Engineering Kyoto University

• Yamashita Masakazu

  Department Of Applied Chemistry Doshisha University

• Watanabe Yoshihisa

  Department Of Basic Geriatrics Graduate School Of Medical Science Kyoto Prefectural University Of Medicine

• Takegami Yoshinobu

  Department of Fuel Chemistry Faculty of Engineering Kyoto University

• Igami Mineo

  Department of Hydrocarbon Chemistry, Faculty of Engineering, Kyoto University

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