The rhodium complex-catalyzed synthesis of quinolines from aminoarenes and aliphatic aldehydes.

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概要

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• A variety of aminoarenes react with aliphatic aldehydes in the presence of a catalytic amount of a rhodium complex and an excess amount of the corresponding nitroarenes at 180 °C to give 2-alkyl- and 2,3-dialkyl-substituted quinolines in excellent yields. Among the rhodium complexes examined, [Rh(norbornadiene)Cl]<SUB>2</SUB> exhibits the highest activity as a catalyst. Thus, 2-methyl-, 2-ethyl-3-methyl-, 2-propyl-3-ethyl-, and 2-butyl-3-propylquinoline derivatives are readily obtained from aminoarenes and ethanal, propanal, butanal, and pent-anal respectively.

• 公益社団法人 日本化学会の論文

著者

• SHIM Sang

  Department of Chemical Engineering, Polymer Technology Institute, Sungkyunkwan University

• Mitsudo Take-aki

  Department Of Energy And Hydrocarbon Chemistry Graduate School Of Engineering Kyoto University

• Watanabe Yoshihisa

  Department Of Basic Geriatrics Graduate School Of Medical Science Kyoto Prefectural University Of Medicine

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