ESR study of cationic radicals in aromatic compound-Cu-AlCl3 systems.
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概要
- 論文の詳細を見る
The electron spin resonance spectra of several aromatic compound–Cu–AlCl<SUB>3</SUB> systems were observed. When benzene, toluene, and ethylbenzene were used as the aromatic compounds, a singlet with a <I>g</I>-value of 2.003 was obtained. In the case of the <I>o</I>-, <I>m</I>-, and <I>p</I>-xylene systems, spectra with well-resolved hfs's resulted. It was suggested that cationic radicals were formed by a transfer of an electron from the benzene ring to Cu(II)–AlCl<SUB>3</SUB>.
- 公益社団法人 日本化学会の論文
著者
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Fukuda Seiji
Department Of Pathology Kumamoto University Medical School
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Hamanoue Kumao
Department Of Chemistry Kyoto Institute Of Technology
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Watanabe Yoshihisa
Department Of Basic Geriatrics Graduate School Of Medical Science Kyoto Prefectural University Of Medicine
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Teranishi Hiroshi
Department of Chemistry, Kyoto Institute of Technology
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Teranishi Hiroshi
Department of Chemistry, Faculty of Technology, Kyoto Institute of Technology
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Imamura Sei-ichiro
Department of Chemistry, Kyoto Institute of Technology
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Fukuda Seiji
Department of Chemistry, Kyoto Institute of Technology
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