The platinum complex catalyzed reductive N-carbonylation of nitroarenes to the carbamates.
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概要
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The platium catalyst combined with triphenylphosphine, tin(IV) chloride, and triethylamine showed high activity for the reductive <I>N</I>-carbonylation of nitroarene in ethanol at 180 °C under carbon monoxide of 60 kg cm<SUP>−2</SUP>. From nitrobenzene, ethyl phenylcarbamate was obtained in 83% yield. Iron(III) chloride, aluminum chloride and titanium(IV) chloride could be used as Lewis acids in place of tin(IV) chloride. Various nitroarenes were transformed into corresponding carbamate in moderate to excellent yields with the platinum catalyst.
- 公益社団法人 日本化学会の論文
著者
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Takeuchi Ryo
Department Of Applied Biological Science Faculty Of Science And Technology Tokyo University Of Scien
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Tsuji Yasushi
Department Of Energy And Hydrocarbon Chemistry Graduate School Of Engineering Kyoto University
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Watanabe Yoshihisa
Department Of Basic Geriatrics Graduate School Of Medical Science Kyoto Prefectural University Of Medicine
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Takeuchi Ryo
Department of Hydrocarbon Chemistry, Faculty of Engineering, Kyoto University
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Suzuki Naoki
Department of Hydrocarbon Chemistry, Faculty of Engineering, Kyoto University
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SUZUKI Naoki
Department of Agricultural Chemistry, Ibaraki University
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