The ruthenium catalyzed synthesis of quinoline derivatives from nitroarenes and aliphatic alcohols.
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概要
- 論文の詳細を見る
Nitroarenes are reductively converted into quinoline derivatives with aliphatic alcohols in the presence of a catalytic amount of ruthenium compound at 180 °C. Ruthenium(III) chloride is the most effective catalyst. The reaction of nitrobenzene with 1-propanol and 1-butanol gave 2-ethyl-3-methylquinoline and 3-ethyl-2-propylquinoline in 65 and 70% yields respectively. <I>p</I>-Methoxynitrobenzene gave 3-ethyl-6-methoxy-2-propylquinoline in 70% yield with 1-butanol. The reaction appears to include the redox reaction between the nitroarenes and the alcohols, that is, a catalytic hydrogen transfer reaction which generates the aminoarenes and aldehydes. Thus, the alcohol plays roles as both a reductant and an aldehyde precursor.
- 公益社団法人 日本化学会の論文
著者
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Tsuji Yasushi
Department Of Energy And Hydrocarbon Chemistry Graduate School Of Engineering Kyoto University
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Watanabe Yoshihisa
Department Of Basic Geriatrics Graduate School Of Medical Science Kyoto Prefectural University Of Medicine
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Shida Jun
Department of Hydrocarbon Chemistry, Faculty of Engineering, Kyoto University
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