Synthesis and Redox Response of Insulated Molecular Wire Elongated through Iron-Terpyridine Coordination Bonds

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概要

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• We synthesized an insulated bridging ligand consisting of a π-conjugated backbone sheathed by permethylated α-cyclodextrin and terpyridyl moieties at either end. This bridging ligand was able to coordinate with Fe2+ to afford an insulated metallopolymer that was elongated through coordination bonds. The molecular wire exhibited a reversible response to a chemical redox stimulus.

著者

• Seki Shu

  Department Of Applied Chemistry Graduate School Of Engineering Osaka University

• Fujihara Tetsuaki

  Department Of Energy And Hydrocarbon Chemistry Graduate School Of Engineering Kyoto University

• Terao Jun

  Department Of Applied Chemistry And Center For Atomic And Molecular Technologies Graduate School Of

• Tsuji Yasushi

  Department Of Energy And Hydrocarbon Chemistry Graduate School Of Engineering Kyoto University

• Masai Hiroshi

  Department Of Energy And Hydrocarbon Chemistry Graduate School Of Engineering Kyoto University

• Matsuda Wakana

  Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University

• Hosomi Takuro

  Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University

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