Titanocene-Catalyzed Reaction of Alkenes and Dienes with Alkyl Halides and Chlorosilanes
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概要
- 論文の詳細を見る
New catalytic reactions for regioselective introduction of alkyl and/or silyl functionalities to alkenes and dienes are described. These reactions proceed efficiently under mild conditions by the use of Cp<SUB>2</SUB>TiCl<SUB>2</SUB> as a catalyst in the presence of Grignard reagents. The present study would provide a prototype for the practical use of alkyl halides and chlorosilanes in transition metal-catalyzed reactions. In these reactions, ate complexes of titanocene play important roles as the active species. The scope and limitations, as well as reaction pathways, are discussed.
- 社団法人 有機合成化学協会の論文
- 2001-11-01
著者
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KAMBE Nobuaki
Department of Applied Chemistry, Graduate School of Engineering, Osaka University
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TERAO Jun
Department of Molecular Chemistry & Science and Technology Center for Atoms, Molecules and Ions Cont
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Terao J
Department Of Applied Chemistry Faculty Of Engineering Osaka University
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Terao Jun
Department Of Applied Chemistry And Center For Atomic And Molecular Technologies Graduate School Of
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Kambe Nobuaki
Department Of Applied Chemistry And Center For Atomic And Molecular Technologies Graduate School Of
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Kambe Nobuaki
Department Of Applied Chemistry Faculty Of Engineering Osaka University
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