Convenient synthesis of .BETA.-silyl ketones from .BETA.-stannyl enol silyl ethers via a (1,4) anionic rearrangement of silicon.
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概要
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The transmetalation (Sn to Li) and [1,4] anionic rearrangement of β-stannyl enol silyl ethers have been achieved, providing a convenient method for synthesis of β-silyl ketones.
- 公益社団法人 日本化学会の論文
著者
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Ogawa Akiya
Department Of Applied Chemistry Faculty Of Engineering Osaka Prefecture University
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Ryu Ilhyong
Department Of Applied Chemistry Faculty Of Engineering Osaka University
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Kambe Nobuaki
Department Of Applied Chemistry And Center For Atomic And Molecular Technologies Graduate School Of
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Sonoda Noboru
Department af Chemical Technology Faculty of Engineering Osaka University
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Nakahira Hiroyuki
Department of Applied Chemistry, Faculty of Engineering, Osaka University
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