Redox Reaction of Tetrahydrofuran Hydroperoxide
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概要
- 論文の詳細を見る
1) Reaction of tetrahydrofuran hydroperoxide with ferrous sulfate produced hexane-1, 6-diol-diformate (13.8%), which was formed by the dimerization of 3-formoxypropyl radical generated from 2-tetrahydrofuranoxy radical, and γ-butyrolactone (31.4%) and 4-hydroxybutanal (trace).<BR>2) In the presence of metal halide, the dimerization of the 3-formoxypropyl radical did not occur and halogenation of the 3-formoxypropyl radical was observed. For example, when tetrahydrofuran hydroperoxide was reacted with cuprous chloride and cupric chloride, 3-formoxypropyl chloride was obtained in a yield of 42.3%.<BR>3) It is worth nothing that under suitable experimental condition the chloro compound was obtained in a good yield.<BR>4) Probable reaction process was discussed.
- 社団法人 日本化学会の論文
著者
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Tsutsumi Shigeru
Department of Chemical Technology Faculty of Engineering Osaka University
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Murai Shinji
Department af Chemical Technology Faculty of Engineering Osaka University
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Sonoda Noboru
Department af Chemical Technology Faculty of Engineering Osaka University
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Murai S.
Department af Chemical Technology Faculty of Engineering Osaka University
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