The Rearrangement Reaction of Levulinic Acid in a Selenium Dioxide-catalyzed Hydrogen Peroxide Oxidation

スポンサーリンク

概要

• 論文の詳細を見る

• The selenium dioxide-catalyzed oxidation of levulinic acid with hydrogen peroxide in <I>t</I>-butyl alcohol gave glutaric acid and methylsuccinic acid as the rearrangement products. The glutaric acid may be formed by the migration of the β-carboxyethyl group to the methyl carbon atom and by the oxidation of the carbonyl group to the carboxyl group, and the formation of methylsuccinic acid may be due to the migration of the methyl group to the methylene carbon atom adjacent to the carbonyl group.

• 社団法人 日本化学会の論文

著者

• Tsutsumi Shigeru

  Department of Chemical Technology Faculty of Engineering Osaka University

• Sonoda N.

  Department of Chemical Technology Faculty of Engineering Osaka University

関連論文

• Studies of the Photochemical Reactions. IV. The Synthesis of Dimethyl-α-tetralylcarbinol by the Photochemical Reaction of Acetone in Tetralin
• Hydrogen Peroxide Oxidation. IV. A New Rearrangement Reaction of Phenyl Alkyl Ketones by Selenium Dioxide Catalyst
• Oxidation of Alicyclic Compounds with Pernitrous Acid
• The Rearrangement Reaction of Levulinic Acid in a Selenium Dioxide-catalyzed Hydrogen Peroxide Oxidation
• Redox Reaction of Tetrahydrofuran Hydroperoxide
• Studies of Photochemical Reaction. VI. The Synthesis of Methylethyl-α-tetrahydrofurylcarbinol and Ethyl-α-tetrahydrofurylcarbinol

スポンサーリンク