Isomerization of Oxygen-substiuted Cyclopropanes by Metal Catalysis
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概要
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Highly regio- and stereospecific isomerization reactions of siloxy- and alkoxycyclopropanes were effected under mild reaction conditions by a variety of metal-catalyzed systems using such as Zn (II), Pt (II), Rh (I), and Ni (0). It is noteworthy that the conversion of siloxycyclopropanes to allyl silyl ethers was established by the use of either zinc iodide or Zeises dimer. The scope, limitations, and mechanisms of isomerization of siloxy- and alkoxy-substituted cyclopropanes are discussed.
- 社団法人 有機合成化学協会の論文
- 2000-11-01
著者
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Sugimura Takashi
Faculty Of Science Himeji Institute Of Technology
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Ryu Ilhyong
Department Of Chemistry Faculty Of Arts And Seiences Osaka Prefecture University
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Ryu Ilhyong
Department Of Applied Chemistry Faculty Of Engineering Osaka University
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