The facile synthesis of N-substituted piperidines from glutaraldehyde and primary amines with tetracarbonylhydridoferrate.

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概要

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• Ethanolic tetracarbonylhydridoferrate solution combined with glutaraldehyde is very efficient for the selective transformation of an amino group into a piperidine ring. A large variety of both aliphatic and aromatic amines react with the ferrate-glutaraldehyde at room temperature under carbon monoxide to give the corresponding <I>N</I>-alkyl- and <I>N</I>-arylpiperidines in good to excellent yields.

• 公益社団法人 日本化学会の論文

著者

• SHIM Sang

  Department of Chemical Engineering, Polymer Technology Institute, Sungkyunkwan University

• Mitsudo Take-aki

  Department Of Energy And Hydrocarbon Chemistry Graduate School Of Engineering Kyoto University

• Yamashita Masakazu

  Department Of Applied Chemistry Doshisha University

• Watanabe Yoshihisa

  Department Of Basic Geriatrics Graduate School Of Medical Science Kyoto Prefectural University Of Medicine

• Takegami Yoshinobu

  Department of Fuel Chemistry Faculty of Engineering Kyoto University

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