The reductive N-methylation of amines with tetracarbonylhydridoferrate-formaldehyde.

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概要

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• Alcoholic tetracarbonylhydridoferrate combined with formaldehyde is an excellent reagent for reductive <I>N</I>-methylation of amines. The effects of reaction conditions such as temperature, atmosphere, and molar ratio (ferrate/formaldehyde/amine) on the reaction have been examined. The optimum condition for <I>N</I>,<I>N</I>-dimethylation of aniline is at 60 °C, under carbon monoxide, and at 1.0/2.2/1.0 for the molar ratio.

• 公益社団法人 日本化学会の論文

著者

• SHIM Sang

  Department of Chemical Engineering, Polymer Technology Institute, Sungkyunkwan University

• Mitsudo Take-aki

  Department Of Energy And Hydrocarbon Chemistry Graduate School Of Engineering Kyoto University

• Yamashita Masakazu

  Department Of Applied Chemistry Doshisha University

• Watanabe Yoshihisa

  Department Of Basic Geriatrics Graduate School Of Medical Science Kyoto Prefectural University Of Medicine

• Takegami Yoshinobu

  Department of Fuel Chemistry Faculty of Engineering Kyoto University

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