Reduction of .ALPHA.,.BETA.-unsaturated carbonyl compounds to the saturated alcohols using hydridocarbonyliron complexes.
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概要
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Tetracarbonylhydridoferrate was found to be effective for the selective reduction of α,β-unsaturated carbonyl compounds to the corresponding saturated alcohols. The reactions proceeded stereospecifically and (−)- and (+)-neodihydrocarveol were obtained exclusively from (+)- and (−)-carvone respectively. The reaction mechanism is briefly discussed.
- 公益社団法人 日本化学会の論文
著者
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Yamashita Masakazu
Department Of Applied Chemistry Doshisha University
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Suemitsu Rikisaku
Department Of Agricultural Chemistry Kyoto University
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Okada Yasuhiro
Department of Applied Chemistry for Resources, Tokyo University of Agriculture and Technology
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Okada Yasuhiro
Department of Applied Chemistry, Faculty of Engineering, Doshisha University
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Miyoshi Kanako
Department of Applied Chemistry, Faculty of Engineering, Doshisha University
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