Liquid-phase oxidation catalyzed by Cu(II)-Cl. III. Oxidation of 1,2,3,4-tetrahydronaphthalene.

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概要

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• 1,2,3,4-Tetrahydronaphthalene was oxidized in the presence of copper(II) acetate in glacial acetic acid. An addition of lithium chloride which formed complexes with copper(II) ion highly accelerated the reaction, and the initiating process was found to be the decomposition of 1,2,3,4-tetrahydro-1-naphthyl hydroperoxide by the copper(II)–chloride ion complexes. However, only about 8% of the decomposition contributed the initiation, and it was suggested that the larger part of the decomposition proceeded through a non-ionic mechanism. Spectrophotometric and ESR experiments suggested that one of the accelerating effects of the chloride ion was due to its action to decompose the inactive copper(II) acetate dimer and form active copper(II)–chloride ion complexes and that the order of the activity of the complexes was CuCl<SUP>+</SUP><CuCl<SUB>2</SUB><CuCl<SUB>3</SUB><SUP>−</SUP>,CuCl<SUB>4</SUB><SUP>2−</SUP>.

• 公益社団法人 日本化学会の論文

著者

• Teramoto Masaaki

  Department Of Chemistry And Material Technology Kyoto Institute Of Technology

• Takegami Yoshinobu

  Department of Fuel Chemistry Faculty of Engineering Kyoto University

• Teranishi Hiroshi

  Department of Chemistry, Faculty of Technology, Kyoto Institute of Technology

• Imamura Sei-ichiro

  Department of Chemistry, Kyoto Institute of Technology

• Sumi Takao

  Department of Chemistry, Kyoto Institute of Technology

• Aomi Hideki

  Department of Chemistry, Kyoto Institute of Technology

• TERAMOTO MASAAKI

  Department of Chemical Engineering, Kyoto University

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