MO Calculation for Interactions of Cu(II) and Co(III) with Hydroperoxides
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概要
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By means of MO calculation, cobalt(III) and copper(II) were considered to decompose primary and secondary hydroperoxides through the oxidative fission of their O–H bond. However, in basic solvents such as pyridine, copper (II) was found to promote the fission of their C–H bond of the α-position by the complex formation with them.
- 公益社団法人 日本化学会の論文
著者
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SAKAKI Shigeyoshi
Department of Applied Chemistry & Biochemistry, Faculty of Engineering, Kumamoto University
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Imamura Sei-ichiro
Department of Chemistry, Kyoto Institute of Technology
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