Equilibrium and Kinetic Studies on Complex Formation Reaction between Crown Ethers and Bivalent Transition Metal Ions.
スポンサーリンク
概要
- 論文の詳細を見る
The complex formation reaction between crown ethers and bivalent transition metal ions was investigated. Although the obtained equilibrium constants were generally small, there was a case where the constant was larger than that for the crown ether–alkali metal system. From kinetic studies the reactions were found to obey the Eigen's mechanism.
- 公益社団法人 日本化学会の論文
著者
-
Matsuyama Hideto
Department Of Chemical Science And Engineering Kobe University
-
Teramoto Masaaki
Department Of Chemistry And Material Technology Kyoto Institute Of Technology
-
Miyake Yoshikazu
Department Of Chemical Energy And Environmental Engineering Faculty Of Environmental And Urban Engin
-
Matsuyama Hideto
Department of Chemistry and Materials Technology, Faculty of Engineering and Design, Kyoto Institute of Technology
-
Arimura Takeo
Department of Chemistry and Materials Technology, Faculty of Engineering and Design, Kyoto Institute of Technology
-
TERAMOTO MASAAKI
Department of Chemical Engineering, Kyoto University
関連論文
- Preparation of Microporous Polypropylene Membrane via Thermally Induced Phase Separation as Support of Liquid Membranes Used for Metal Ion Recovery
- ENHANCEMENT IN EXTRACTION RATES BY ADDITION OF ORGANIC ACIDS TO AQUEOUS PHASE IN SOLVENT EXTRACTION OF RARE EARTH METALS IN PRESENCE OF DIETHYLENETRIAMINEPENTAACETIC ACID
- ANALYSIS OF EXTRACTION RATE AND SELECTIVITY OF Pr/Nd SEPARATION BY SOLVENT EXTRACTION IN THE PRESENCE OF DIETHYLENETRIAMINEPENTAACETIC ACID IN AQUEOUS PHASE
- EQUILIBRIUM AND NON-EQUILIBRIUM EXTRACTION SEPARATION OF RARE EARTH METALS IN PRESENCE OF DIETHYLENETRIAMINEPENTAACETIC ACID IN AQUEOUS PHASE
- DISSOCIATION RATES OF VARIOUS HEAVY RARE EARTH METAL-DIETHYLENETRIAMINEPENTAACETIC ACID COMPLEXES
- Education and research in Center for Membrane and Film Technology and Research Organization for Membrane and Film Technology
- Spectral Changes of Lysozyme Adsorbed on Ultrafine Silica Particles
- The Effect of Polymer Molecular Weight on the Structure of a Honeycomb Patterned Thin Film Prepared by Solvent Evaporation
- Silver-mediated separation of polyunsaturated fatty acids by oil-in-water emulsion liquid membranes
- Kinetics of Magnetite Formation in a Three-Phase System
- Kinetics of Ferrite Formation in a Three-Phase System
- FORMATION OF PERCOLATED STRUCTURE DURING SOLVENT CASTING OF POLYMER BLEND-SOLVENT SYSTEMS
- Kinetics of Photo-Induced Reduction of m-Nitroacetophenone with TiO_2 Powder
- The Formation Process of Spherical Mesoporous Silica with Reverse Nanostructure of MCM41 in a Two-phase System
- Synthesis of Ordered Cage-like Mesoporous Aluminosilicates from Na-A Zeolite Precursors Dissolved in HCl
- Mesoporous Titania Prepared in the Presence of Alkylamine
- Photocatalytic Degradation of Methylene Blue with Metal-Doped Mesoporous Titania under Irradiation of White Light
- Synthesis and Characterization of Ni-doped Silica Membranes Prepared Using a Hybrid Sol-Gel/CVD Method
- Carbon Dioxide Adsorption Properties in Ion-exchanged Zeolites Rho
- Kinetic studies of exchance reactions between rare earth metal ions and their diethylenetriaminepentaacetic acid complexes.
- Selective separation of rare earth metals by Donnan dialysis in the presence of water-soluble complexing agent.
- Extraction mechanism of rare earth metals in the presence of diethylenetriaminepentaacetic acid in aqueous phase.
- EVALUATION OF MASS TRANSFER EFFECTS ON CONSECUTIVE CATALYTIC REACTION USING AN INTERNAL-RECYCLE CATALYTIC REACTOR
- THE EFFECTS OF MASS TRANSFER ON THE SELECTIVITY OF GAS-LIQUID REACTIONS
- Extraction of amine by W/O/w emulsion system.
- Facilitated transport of CO2 through supported liquid membranes of various amine solutions-effects of rate and equilibrium of reaction between CO2 and amine-.
- Measurement of Rate Constant of Reaction between Carbon Dioxide and Monoprotonated Ethylenediamine by Chemical Absorption Method.
- Effect of facilitated diffusion in internal aqueous droplets on effective diffusivity and extraction rate of phenol in emulsion liquid membranes.
- Separation of ethylene from ethane by supported liquid membranes containing silver nitrate as a carrier.
- Kinetics of ozonation of aldehydes in relation to their ozone-initiated autoxidation.
- Equilibrium and Kinetic Studies on Complex Formation Reaction between Crown Ethers and Bivalent Transition Metal Ions.
- Overall rate of ozone oxidation of cyanide in bubble column.
- Absorption of dilute nitric monoxide in aqueous solutions of Fe(II)-EDTA and mixed solutions of Fe(II)-EDTA and Na2SO3.
- Liquid-phase oxidation catalyzed by Cu(II)-Cl. III. Oxidation of 1,2,3,4-tetrahydronaphthalene.
- Permeation rate and selectivity in the separation of cobalt and nickel by supported liquid membranes.
- Simultaneous absorption and/or desorption of hydrogen sulphide and ammonia.
- Effect of alkyl chain length of o-hydroxyoxime on the extraction of copper.
- Effect of dissociation on the absorption rate of dilute SO2.
- Mechanism and kinetics of palladium extraction with .BETA.-hydroxyoxime.
- SELECTIVITY OF CONSECUTIVE GAS-LIQUID REACTIONS
- EFFECT OF MASS TRANSFER ON THE SELECTIVITY OF (m, n)-(p, q) ORDER CONSECUTIVE GAS-LIQUID REACTIONS