Distribution Coefficients of Various Impurities in Alkali Halides
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概要
- 論文の詳細を見る
Distribution coefficients of several monovalent and divalent impurities were obtained for NaCl, KCl, NaBr and KBr by the method of zone melting performed in the respective halogen atmosphere. Dependence of the impurity distribution on the speed of a a zone pass and on the concentration of impurity were studied in KC1 doped with lead ions, whose concentration was determined by the measurements of optical absorption as well as by the usual chemical analysis. For the monovalent impurities, the distribution coefficients obtained from distribution curves agree well with those calculated from the thermodynamical expression of distribution coefficient using the theoretical energy of solid solution. The energy of solid solution of divalent impurities was calculated from the experimentally obtained distribution coefficients taking the equilibrium of Schottky defects into account and was compared with that of lattice calculation.
- 社団法人応用物理学会の論文
- 1968-08-05
著者
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Ikeya Motoji
Department Of Earth And Space Science Graduate School Of Science Osaka University
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Ikeya Motoji
Department Of Nuclear Engineering Nagoya University
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ITOH Noriaki
Department of Physics, Faculty of Science, Nagoya University
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Ikeya Motoji
Department Of Earth And Space Science Faculty Of Science Osaka University
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SUITA Tokuo
Department of Nuclear Engineering, College of Engineering, Osaka University
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Suita Tokuo
Department Of Nuclear Engineering Osaka University
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Suita Tokuo
Department Of Atomic Energy Engineering Faculty Of Engineering Osaka University
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Itoh Noriaki
Department Of Crystalline Material Science Faculty Of Engineering Nagoya University
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