New Aspects of the Aromatic Photosubstitution with Iodopyridines

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概要

• 論文の詳細を見る

• Reactive entities in the photoreaction of 2-, 3- and 4-iodopyridines with substituted benzenes were investigated; 3- and 4-pyridylation could be explained in terms of radical reaction, while the 2-pyridyl cation was an important intermediate in the 2-pyridylation. The importance of the unshared electron pair of the nitrogen adjacent to the radical carbon for the conversion of the 2-pyridyl radical initially produced into the cation is discussed on the basis of molecular orbital (MO) calculations.

• 公益社団法人日本薬学会の論文
• 1993-11-15

著者

• 金岡 祐一

  Faculty of Pharmaceutical Sciences, Hokkaido University

• 関 興一

  北海道医療大学 薬学部

• Ohkura Kazue

  Faculty Of Pharmaceutical Sciences Health Sciences University Of Hokkaido

• 金岡 祐一

  Toyama Women's College

• 寺島 正直

  Faculty of Pharmaceutical Sciences, Higashi-Nippon-Gakuen University

• 大倉 一枝

  Faculty of Pharmaceutical Sciences, Health Sciences University

• 関 興一

  Faculty of Pharmaceutical Sciences, Health Sciences University

• 寺島 正直

  Faculty Of Pharmaceutical Sciences Higashi-nippon-gakuen University

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