Chemical Transformation of Terpenoids. VIII. Anodic Oxidation of Geranyl Acetate

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概要

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• Constant-current electrolysis of geranyl acetate (2) in CH_3CN-H_2O afforded eight oxidation products (3-10) which were presumed to be formed through initial oxidation of the double bond at C_6-C_7. Based on the results of electrolysis of 2 in CH_3CN-H_2^<18>O, we have found that the oxygen atom(s) in the products (3-10) is(are) derived from water used as the reaction medium.

• 公益社団法人日本薬学会の論文
• 1991-05-25

著者

• 北川 勲

  Faculty of Pharmaceutical Sciences, Osaka University

• 渋谷 博孝

  Faculty of Pharmaceutical Sciences, Osaka University

• 村上 啓寿

  Faculty Of Pharmaceutical Sciences Osaka University

• 北川 勲

  Faculty Of Pharmaceutical Sciences Osaka University

• 嶋田 富貴子

  Faculty of Pharmaceutical Sciences, Osaka University

• 村上 啓寿

  Faculty Of Pharmaceutical Sciences Nagoya City University:(present Address)kyoto Pharmaceutical Univ

• 嶋田 富貴子

  大阪大学薬学部

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