THE ABSOLUTE STEREOSTRUCTURE OF (4S, 5S)-(+)-GERMACRONE 4,5-EPOXIDE FROM ZEDOARIAE RHIZOMA CULTIVATED IN YAKUSHIMA ISLAND

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概要

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• (4S, 5S)-(+)-Germacrone 4,5-epoxide (2) has been isolated as a characteristic constituent from Zedoariae Rhizoma, the air-dried zedoary cultivated in Yakushima Island in Japan, and the absolute stereostructure (2) has been determined from the spectral properties, X-ray analysis, and CD spectra. The epoxide (2) seems to be a biogenetically key compound for various germacrane-sesquiterpenoids in zedoary.

• 公益社団法人日本薬学会の論文
• 1984-05-25

著者

• 北川 勲

  Faculty of Pharmaceutical Sciences, Osaka University

• 渋谷 博孝

  Faculty of Pharmaceutical Sciences, Osaka University

• 北川 勲

  Faculty Of Pharmaceutical Sciences Osaka University

• 柳 和則

  Takatsuki Research Laboratory, Sumitomo Chemical Co., Ltd.

• 吉原 実

  大阪大学薬学部

• 柳 和則

  Takatsuki Research Laboratory Sumitomo Chemical Co. Ltd.

• 吉原 実

  Faculty of Pharmaceutical Sciences, Osaka University

• 北野 栄作

  Faculty of Pharmaceutical Sciences, Osaka University

• 北野 栄作

  大阪大薬

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