Biogenetically Patterned Transformation of Eudesmanolide to Eremophilanolide. IV. Conversion of Alantolactone to Several Furanoeremophilane Derivatives
スポンサーリンク
概要
- 論文の詳細を見る
Biogenetic-type conversions of an eudesmane-type sesquiterpene alantolactone (4) to several furanoeremophilanes (10a, 10b, 12a, 12b) including naturally occurring 6-acetoxy-1,10-epoxy-euryopsin (12b) have been accomplished. The conversions constitute the formal total syntheses of these furanoeremophilanes via the biogenetic-type angular methyl migration of the eudesmane-type precursor. It has been also demonstrated that the biogenetic-type transformation starting from the eudesmane-type 5α, 6α-epoxide may be a useful process in the synthetic pathway of eremophilane-type sesquiterpene.
- 公益社団法人日本薬学会の論文
- 1977-10-25
著者
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北川 勲
Faculty of Pharmaceutical Sciences, Osaka University
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渋谷 博孝
Faculty of Pharmaceutical Sciences, Osaka University
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北川 勲
Faculty Of Pharmaceutical Sciences Osaka University
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河井 真知子
Faculty Of Pharmaceutical Sciences Osaka University
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