Metabolic Products of Fungi. XVIII. On the Structure of Lumiluteoskyrin.

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概要

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• The structure of a photo-reaction product of luteoskyrin, designated lumiluteoskyrin, has been discussed. Lumiluteoskyrin, C_<30>H_<20>O_<12>, dark purple crystals, m. p. above 360°, yielded a diacetate, C_<30>H_<18>O_<10> (OCOCH_<3>)_2,a tetraacetate, C_<30>H_<16>O_6 (OCOCH_3)_4,and a hexa acetate, C_<30>H_<14>O_6 (OCOCH_3)_6. On thermal degradation, lumiluteoskyrin gave islandicin and catenarin. On reduction with alkaline sodium dithionite, lumiluteoskyrin was not cleaved, while by the action of hydrochloric acid and zinc, it yielded islandicin. The positive magnesium acetate reaction and the ultraviolet and visible light absorption spectra showed that lumiluteoskyrin is a true quinone compound possessing a naphthazarin system in its molecule. On the basis of the chemical and spectral evidences, a structural formula (III) was proposed for lumiluteoskyrin and the photo-reaction mechanism was discussed.

• 公益社団法人日本薬学会の論文
• 1961-05-25

著者

• 北川 勲

  Faculty of Pharmaceutical Sciences, Osaka University

• 柴田 承二

  Faculty of Pharmaceutical Sciences, University of Tokyo

• 柴田 承二

  東京大学

• 北川 勲

  Faculty Of Pharmaceutical Sciences Osaka University

• 北川 勲

  東大薬:(現)大阪大学薬学部

• 柴田 承二

  東京大学名誉教授 日本学士院会員

• 柴田 承二

  Faculty Of Pharmaceutical Sciences University Of Tokyo

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