Characteristics of Lipase Modified with Water-soluble Acylating Reagents and Its Esterification Ability

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概要

• 論文の詳細を見る

• Lip was modified with various hydrophobic groups, such as Z, Boc, lauroyl, and palmitoyl, using water-soluble acylating reagents. The chemical modification enhanced the dispersibility of Lip in organic solvents, and changed the substrate selectivity, which depends on the length of the carbon chain of triglycerides in hydrolytic reactions. As for the synthesis of triglycerides, Z-modified Lip catalyzed this reaction faster than unmodified Lip. Z-, Boc-, and fatty acid-modified Lips also catalyzed diverse esterification reactions including that of ethyl eicosapentaenoate, lactose oleate, and cholesterol oleate, and the yields of these reactions increased depending on the carbon number of the introducing group.

• 社団法人日本農芸化学会の論文
• 1995-05-23

著者

• 高橋 康弘

  埼玉大学大学院理工学研究科分子生物学領域

• KAWASAKI Yoshihiro

  Technology and Research Institute, Snow Brand Milk Products Co., Ltd.

• Tanaka Kaori

  Department Of Pharmaceutics Faculty Of Pharmaceutical Sciences Kobe-gakuin University

• Tanaka Kaori

  Department Of Fermentation Technology Faculty Of Engineering Hiroshima University

• TAKAHASHI Yoshinori

  Department of Chemistry, Faculty of Science, Tokyo University of Science

• OKAI Hideo

  Department of Fermentation Technology, Faculty of Engineering, Hiroshima University

• KAWASAKI Yoshihiro

  Fujitsu Laboratories Ltd., Wireless Communication Systems Laboratories

• Kawasaki Yoshihiro

  Technical Research Institute Snow Brand Milk Products Co. Ltd.

• Kawasaki Yoshihiro

  Fujitsu Laboratories Ltd. Wireless Communication Systems Laboratories

• Kawasaki Yoshihiro

  Technical Research Institute Snow Brand Milk Products Co.

• Kawasaki Y

  Snow Brand Milk Products Co. Ltd. Saitama Jpn

• Tatsumi K

  National Inst. Advanced Industrial Sci. Ibaraki Jpn

• Murakami Mototake

  Technical Research Institute, Snow Brand Milk Products Co., Ltd.

• Kawanari Masami

  Technical Research Institute, Snow Brand Milk Products Co., Ltd.

• Tatsumi Kiyoshi

  Technical Research Institute, Snow Brand Milk Products Co., Ltd.

• Okai H

  Hiroshima Univ. Hiroshima Jpn

• Okai Hideo

  Department Of Fermentation Technology Faculty Of Engineering Hiroshima University

• Kawanari Masami

  Technical Research Institute Snow Brand Milk Products Co. Ltd.

• Murakami Mototake

  Technical Research Institute Snow Brand Milk Products Co. Ltd.

• Tatsumi Kiyoshi

  Technical Research Institute Snow Brand Milk Products Co. Ltd.

• Takahashi Yoshinori

  Department Of Applied Physics Faculty Of Engineering Nagoya University

• Takahashi Yoshinori

  Department Of Applied Chemistry Faculty Of Science And Technology Keio University

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