Full Multiple-Scattering Approach to Na K-Edge XANES of NaCl-KCl Mixed Crystal

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概要

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• In this work we studied the Na K-edge XANES spectra of pure Nail crystal andNaCl-KCI mixed crystal measured by Murata et al. to clarify the geometric and elec-tronic structure around X-ray absorbing atoms by use of the short-range order fullmultiple scattering calculation. The changes observed in the experimental XANES forthe increase of KCI concentration are qualitatively explained by assuming that in avery small scale Nail and KCI grains are to be in contact with each other. We alsofound that the Na-Cl distance in the boundary region remains nearly the same as inNail crystal. The net charge on Na ion in pure Nail crystal is also estimated andfound to be slightly smaller than that in NaF crystal.

• 社団法人日本物理学会の論文
• 1989-08-15

著者

• MATSUKAWA Tokuo

  Department of Physics, Faculty of Science, Naruto University of Education

• Yamasaki K

  Faculty Of Engineering Yokohama National University

• FUJIKAWA Takashi

  Faculty of Engineering,Yokohama National University

• OKAZAWA Toshinaga

  Faculty of Engineering,Yokohama National University

• YAMASAKI Kazuo

  Faculty of Engineering,Yokohama National University

• TANG Jing-Chang

  Faculty of Engineering,Yokohama National University

• MURATA Takatoshi

  Department of Physics,Kyoto University of Education

• NAOE Shun-ichi

  Department of Physics,College of Liberal Arts,Kanagawa University

• Yamasaki Kazuo

  Faculty Of Engineering Yokohama National University

• Tang Jing-chang

  Faculty Of Engineering Yokohama National University

• Naoe´ S

  Department Of Physics College Of Liberal Arts Kanagawa University

• Naoe Shun-ichi

  Department Of Physics Faculty Of Science Kyoto University

• Matsukawa T

  National Institute Of Advanced Industrial Science And Technology

• Fujikawa Takashi

  Faculty Of Engineering Yokohama National University

• Matsukawa T

  Kwansei Gakuin Univ. Nishinomiya

• Matsukawa Tokuo

  Department Of Physics College Of General Education Osaka University

• Murata Takatoshi

  Department Of Oral Health School Of Life Dentistry Nippon Dental University

• YAMASAKI Katsuhito

  Department of Physics,Faculty of Science,Osaka University

• Okazawa Toshinaga

  Faculty Of Engineering Yokohama National University

• Fujikawa Takashi

  Faculty Of Agriculture Shizuoka University

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