Electron Paramagnetic Resonance Study of Ag^<++> Ions in CdCl_2
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概要
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The EPR spectra of a Ag^<++> ion in CdCl_2 are studied at liquid nitrogen temperature and at room temperature. The Ag^<++> ion is found at the center of the octahedron of sic Cl^- ions. The octahedron of Cl^- ions is elongated tetragonally due to a Jahn-Teller effect at liquid nitrogen temperature. It is also observed that the principal axis of the g-tensor deviates from a line joining the Ag^<++> ion and one of the nearest neighbor Cl^- ions towards the crystal c-axis. This deviation is interpreted to be due to the influence of the axial symmetry field parallel to the c-axis on the Jahn-Teller effect. At room temperature a single broad EPR line with axial symmetry is observed.
- 社団法人日本物理学会の論文
- 1972-06-05
著者
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Matsumoto Hiroaki
Department Of Cardiology Osaka Medical Center For Cancer And Cardiovascular Diseases
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Naoe Shun-ichi
Department Of Physics Faculty Of Science Kyoto University
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Miyanaga Takeshi
Department Of Physics Faculty Of Educaiton Wakayama University
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Matsumoto Hiroaki
Department Of Applied Chemistry Graduate School Of Engineering Osaka Prefecture University
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Matsumoto Hiroaki
Department Of Electronics Faculty Of Engineering Fukui University
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