Quantum Statistical Approach to Debye-Waller Factors in EXAFS,EELS and ARXPS. : VI. Path-Integral Approach to Morse Potential Systems
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概要
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In this pajcer t1aeruaatt[ ef['ects itu X-ray Pltotoelectrot'n Difln'zxction (XPD) arad BXAFS dtre toatozaaic vibrartion in lNIor'se )cotential ;xre stvrdied toy LIST of' Clue Feynznan ' s patla integr?tl apjor'ottch.Tl?is stpproatch C'2[l1 be atpjclied to strouagly ;rtula;tr'rtaoruic systetaas x'x'here tlae ctrtaatrlanat 2lll2llN'S(2S lcreatk.It is closely related to tl?e xvel[-kraoxvra cJstssic?tl ajvjcroacla xvlaich is orxly x'alid at laigl'a terarper'attrre.Tlte pluase of' Line thet'uaasxl ['?tctor jclst3 ' S 2111 itarjcortsxtat role botl? in XPD stnd EXAF S anatl)'ses for tlaeatsyuaaraaetric ]Xlorse jcotenti?tl. At 1aigJt tettaperatttrre e;xclt ctrrtattlant integr?tl dixverges NV11CIC2lS tl?eclassical ajcproxiraa;ttion is s?rtisfstctor5' tooth f'or the plaase atzad tJte thert'ta?tl danaaping. On the otherJaand, ztt Joxv tettapers?tvrr'e ctrraatrlsrnts exp;tnasioru conx'erges ])(2C21L1S0of' tJae qtr?tnttrttt fltzcttnartionFor' the descrijctiora of' tJae plaztse Ulp to tlae third, ;rnd ['or tlaatt of the theruaaal dataaping Llp to the['otrrth cvrrtatrl?tnt shotrld Ice t?tI<en itato 2lCCOLl[lC. Ita this ca,se tlae cJstssical approxitaa?xtiora is qtritejcoor f'or the descn'iptioua of' tlae txx'o factors. For the qtrarattruaa csrlctrlattiotu xx'itlu Cite xx'e?tk qtmazatttataeffect tlae ttrnneling does not cotatri}otrte to tlae joeaak slaift irt tlae prob;t1.>ility detasity P(q) btrt (oflue laroadening.
- 社団法人日本物理学会の論文
- 1998-08-15
著者
-
Miyanaga Takafumi
Faculty Of Science And Technology Hirosaki University
-
Fujikawa Takashi
Faculty Of Engineering Yokohama National University
-
Fujikawa Takashi
Faculty Of Agriculture Shizuoka University
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