X-Ray K Absorption Edge Structures of Chlorine Ion in [CoCl_2(en)_2]NO_3,[CoCl_2(en)_2]Cl and [Co (en)_3]Cl_3・3H_2O
スポンサーリンク
概要
- 論文の詳細を見る
X-rx'z K absorrtion edxe structures of chlorine ton in trans-[CoCJz(en)z]N0s,trans-[CoCl.(en).]Cl and [Co(en).]Cl. - 3H.0 are measured with a high-resolutionvacuum two-crystal spectrometer. The spectra, except that of [Co(en)3]C13 ' 3H.0having no ligand Cl ion, show an extremely narrow absorption line at the absorp-tion threshold. All of the spectra show a broad absorption band extending to thehigher energy region of the narrow absorption line. It is found that a charac-teristic of the respective spectra depends on the different chemical states betweenthe cobalt and chlorine tons. The result is interpreted on the basis of molecularorbital theory.
- 社団法人日本物理学会の論文
- 1984-12-15
著者
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MATSUKAWA Tokuo
Department of Physics, Faculty of Science, Naruto University of Education
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Matsukawa T
National Institute Of Advanced Industrial Science And Technology
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OBASHI Masayoshi
Department of Physics, College of General Education, Osaka University
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Matsukawa T
Kwansei Gakuin Univ. Nishinomiya
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Matsukawa Tokuo
Department Of Physics College Of General Education Osaka University
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Obashi M
Department Of Physics College Of General Education Osaka University
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Obashi Masayoshi
Department Of Physics College Of General Education Osaka University
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