Selective <I>p</I>-Toluenesulfonylation of <I>myo</I>-Inositol Derivatives

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概要

• 論文の詳細を見る

• Attempt to know the reactivities, toward sulfonylation, of the hydroxyl groups in <I>myo</I>-inositol was carried out using partially sulfonylated derivatives of <I>myo</I>-inositol. The present studies indicated that the order of reactivity of the hydroxyl groups is 1-OH and 3-OH>4-OH and 6-OH>5-OH>2-OH. From a preparative standpoint, 1,3–di-<I>O</I>-<I>p</I>-toluenesulfonyl-<I>myo</I>-inositol was readily obtained in 59% yield from 1-<I>O</I>-<I>p</I>-toluenesulfonyl-<I>myo</I>-inositol by a selective sulfonylation.

• 公益社団法人 日本化学会の論文

著者

• Ogawa Seiichiro

  Department Of Applied Cemistry Faculty Of Science And Technology Keio University

• Suami Tetsuo

  Department of Applied Chemistry Faculty of Engineering Keio University

• Oki Shuichi

  Department of Applied Chemistry, Faculty of Engineering, Keio University

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