Aminocyclitols. 34. Synthesis of inosadiamine-1,4 derivatives.

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概要

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• Three new inosadiamine-1,4 derivatives have been prepared by nitromethane cyclization of a dialdehyde obtained by periodate oxidation of 1,4-di-<I>O</I>-methyl-(l,2,3,4,5/0)-5-acetamido-l,2,3,4-cyclopentanetetrol. The cyclization product was catalytically hydrogenated and subsequently acetylated to give three inosadiamine derivatives. Their structures were established by PMR spectra as <I>myo</I>-2,5, <I>epi</I>-1,4, and <I>cis</I>-inosadiamine-1,4 derivatives.

• 公益社団法人 日本化学会の論文

著者

• Shiratori Takaaki

  Department Of Anesthesia Sendai Social Security Hospital Japan

• Suami Tetsuo

  Department of Applied Chemistry Faculty of Engineering Keio University

• Shiratori Takaaki

  Department of Applied Chemistry, Faculty of Engineering, Keio University

• Tadano Kinnichi

  Department of Applied Chemistry, Faculty of Engineering, Keio University

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