Aminocyclitols. 36. Chlorination and dechlorination of aminocyclitol and inositol derivatives. Preparation of dideoxy- and trideoxystreptamines.

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概要

• 論文の詳細を見る

• Chlorination of four aminocyclitol and six inositol derivatives with sulfuryl chloride gave the chloro substitution products, which were then dechlorinated by hydrogenolysis with Raney nickel or by treatment with tributyltin(IV) hydride giving the corresponding deoxy compounds. Several useful aminocyclitols, including 2,4-dideoxy- and 2,4,5-trideoxystreptamines, were prepared from 2-deoxystreptamine derivatives by these procedures.

• 公益社団法人 日本化学会の論文

著者

• IWATA KEIJI

  Department of Cardiovascular Surgery, Osaka National Hospital

• Fujimori Hitoshi

  Department Of Internal Medicine School Ot Medicine Keio University

• Ogawa Seiichiro

  Department Of Applied Cemistry Faculty Of Science And Technology Keio University

• Suami Tetsuo

  Department of Applied Chemistry Faculty of Engineering Keio University

• Kasuga Akira

  Department of Applied Chemistry, Faculty of Engineering, Keio University

• Hongo Yuji

  Department of Applied Chemistry, Faculty of Engineering, Keio University

• Fujimori Hitoshi

  Department of Applied Chemistry, Faculty of Engineering, Keio University

• Iwata Keiji

  Department of Applied Chemistry, Faculty of Engineering, Keio University

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