Cyclobutyl Cation Rearrangements of 6-Protoilluden-8α-ol, 7-Protoilluden-6-ol and Related Compounds(Organic,Chemical)
スポンサーリンク
概要
- 論文の詳細を見る
6-ProtoilIuden-8α-ol (15) was formolyzed and then reduced with LiAlH_4 to give 7-protoil-luden-6-ol (16) and its stereoisomer (17). 3-epi-6-Protoilluden-8α-ol (19) also gave the same products under the same conditions. These and other related reactions imply that the 7-protoilludene C-6 cation (10) is an important intermediate in the biosynthesis of illudane (11), marasmane (12) and illudalane (13) type sesquiterpenes.
- 社団法人日本薬学会の論文
- 1987-07-25
著者
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奥田 重信
Institute of Applied Microbiology, University of Tokyo
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岩崎 成夫
東京大学分子細胞生物学研究所
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森崎 尚子
東大・分生研
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野副 重男
Pharmaceutical Institute, Tohoku University
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岩崎 成夫
Institute of Molecular and Cellular Biosciences, The University of Tokyo
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岩崎 成夫
Institute Of Applied Microbiology The University Of Tokyo
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古川 淳
(present Address)exploratory Research Laboratories Ii Daiichi Pharmaceutical Co. Ltd.
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森崎 尚子
Institute of Applied Microbiology, The University of Tokyo
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古川 淳
Institute of Applied Microbiology, The University of Tokyo
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小林 久芳
Institute of Applied Microbiology, The University of Tokyo
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奥田 重信
東大応微研
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奥田 重信
Institute Of Applied Microbiology The University Of Tokyo
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野副 重男
Pharmaceutical Institute Tohoku University
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古川 淳
Institute Of Applied Microbiology University Of Tokyo
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小林 久芳
Institute Of Applied Microbiology University Of Tokyo
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