Studies on the Constituents of Chloranthus spp. III. Six Sesquiterpenes from Chloranthus japonicus
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概要
- 論文の詳細を見る
Six sesquiterpene lactones (I-VI) were isolated and characterized as constituents of Chloranthus japonicus (Chloranthaceae). The lactones chloranthalactone A-E (I-V) were found to be lindenane derivatives, and the lactone VI was identified as atractylenolide III. The structure of chloranthalactone C (III) was determined by X-ray crystallographic analysis of a crystal of III in conjunction with the negative Cotton effect in the optical rotatory dispersion (ORD) curve and negative circular dichroism curve of the ketoalcohol (XII) prepared from III. The stereostructures of chloranthalactone A and B (I and II) were deduced from the ORD curves of the degradation products (VII and X). The cytotoxicities of these lactones against mouse lymphosarcoma L-5178Y cells were determined in comparison with that of helenalin, and they were found to show moderate cytotoxic effects.
- 公益社団法人日本薬学会の論文
- 1980-01-25
著者
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小池 隆
大阪薬科大学
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草野 源次郎
Osaka University Of Pharmaceutical Sciences
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竹本 常松
Faculty of Pharmacy, Tokushima Bunri University
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野副 重男
Pharmaceutical Institute, Tohoku University
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竹本 常松
徳島文理大・薬
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甲 千寿子
Instrumental Analysis Center For Chemistry Faculty Of Sciences Tohoku University
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野副 重男
Pharmaceutical Institute Tohoku University
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内田 正顕
東北大学薬学部
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近藤 嘉和
Pharmaceutical Institute Tohoku University
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甲 千寿子
Department of Chemistry, Faculty of Science, Tohoku University
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近藤 嘉和
東北大学薬学部
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竹本 常松
Faculty Of Pharmaceutical Sciences Tokushima University Of Arts And Sciences
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内田 正彰
東北大学薬学部
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