Benzylcarbonyl化合物とFormamideとの反応(第3報)

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概要

• 論文の詳細を見る

• Unlike α-acyl-3,5-dimethoxyphenylacetonitriles, α-acyl-m-methoxyphenylacetonitriles (Ia, b, c, and d) gave 4-amino-5-arylpyrimidines (IIa, b, c, and d) and m-methoxyphenylacetonitrile (III) on being heated with H_2NCHO and POCl_3. In the case of α-benzoyl-m-methoxyphenylacetonitrile (Id), β-amino-α-(m-methoxyphenyl)cinnamonitrile (IV), the intermediate of pyrimidine synthesis, and benzamide (V) were also isolated. III or IV gave IIa or IId under more drastic conditions. Like III, 3,5-dimethoxyphenylacetonitrile (VI) gave 4-amino-5-arylpyrimidine (VII) by analogous treatment.

• 公益社団法人日本薬学会の論文
• 1969-10-25

著者

• 廣田 喬

  Faculty Of Pharmaceutical Sciences Okayama University

• 大和 正利

  第一薬科大学

• 小山 鷹二

  熊本大学薬学部

• 戸田 睦子

  熊本大学薬学部

• 廣田 喬

  熊本大学薬学部

• 岩井 勝正

  熊本大学薬学部

• 南 基成

  熊本大学薬学部

関連論文

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• Reaction of Benzoxazoline-2-thiones with Alkyl Halides
• Polycyclic N-Hetero Compounds. VI. Synthesis of 11,13,15-Triazasteroidal Compounds and Correction of the Structures of Its Intermediates
• Polycyclic N-Hetero Compounds. II, Synthesis of 11,13,15-Triazasteroidal Skeleton
• Syntheses of 3-Substituted 1-Methyl-6-phenylpyrimido[5,4-e]-1,2,4-triazine-5,7(1H, 6H)-diones (6-Phenyl Analogs of Toxoflavin) and Their 4-Oxides, and Evaluation of Antimicrobial Activity of Toxoflavins and Their Analogs
• Polycyclic N-Hetero Compounds. XVI. Reactions of Benzyl Ketones with Formamide or Acetamide
• Benzylcarbonyl化合物とFormamideとの反応.VIII.m-位にMethyl基を有するα-Acylphenylacetonitrileの反応
• Polycyclic N-Hetero Compounds. VIII. Reactions of Ketones with Trisformylaminomethane
• Polycyclic N-Hetero Compounds. VII. Reactions of Benzyl Ketones with Formamide XI
• Polycyclic N-Hetero Compounds. XVII. Reactions of Heterocyclic Active Methyl Group with Formamide or Trisformylaminomethane
• Polycyclic N-Hetero Compounds. XV. The Vilsmeier Reaction of Phenylacetonitriles. II
• Polycyclic N-Hetero Compounds. IV. Reactions of 4-Amino-5-arylpyrimidines with Dimethyl Sulfoxide
• Benzylcarbonyl化合物とFormamideとの反応(第9報)α-Acyl-5,6,7,8-tetrahydro-2-naphthylacetonitrileとの反応
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• Polycyclic N-Hetero Compounds. III. Synthesis of 1,3,10-Triazaphenanthrenes
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