生体触媒の利用とその新展開.キラルテンプレートの創製と不斉合成への応用
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概要
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The use of biocatalysts for the preparation of new chiral synthons has provided a novel synthetic route to the useful natural products. A method for the preparation of chiral carbocyclic alcohols has been also developed by utilizing the Pseudomonas fluorescens lipase (PFL)-catalyzed enantioselective hydrolysis. The above-mentioned alcohols have been found to be effective as chiral auxiliaries for asymmetric reactions.
- 1992-07-25
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