A NEW SYNTHETIC ROUTE TO METHYL (-)-SHIKIMATE BY ASYMMETRIC DIELS-ALDER REACTION OF (S__-)_S-3-(2-PYRIDYLSULFINYL)ACRYLATE
スポンサーリンク
概要
- 論文の詳細を見る
A 7-oxabicyclo[2.2.1]heptene derivative (<7a>___-) that substituted effectively for the synthesis of (-)-shikimic acid was prepared by an asymmetric Diels-Alder reaction of (S__-)_S-3-(2-pyridylsulfinyl)acrylate (2__-) with 3,4-dibenzyloxyfuran (4__-). The bicyclic compound (<7a>___-) was converted to methyl (-)-triacetylshikimate (<14>___-) <via>___- the <endo>___--<cis>___- dibenzyloxy derivative (<11>___-).
- 社団法人日本薬学会の論文
- 1988-08-25
著者
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小泉 徹
富山医科薬科大学薬学部薬化学
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小泉 徹
Faculty Of Pharmaceutical Sciences Toyama Medical And Pharmaceutical University
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竹内 義雄
富山大院医薬
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竹内 義雄
Faculty Of Pharmaceutical Sciences University Of Tokyo
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Koizumi T
Faculty Of Pharmaceutical Sciences Toyama Medical And Pharmaceutical University
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高橋 たみ子
富山医科薬科大学薬学部薬化学
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高橋 たみ子
Faculty of Pharmaceutical Sciences, Toyama Medical and Pharmaceutical University
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波木 利志栄
Faculty of Pharmaceutical Sciences, Toyama Medical and Pharmaceutical University
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小泉 徹
Department Of Synthetic Organic Chemistry:faculty Of Pharmaceutical Sciences Toyama Medical And Phar
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Koizumi Toru
Faculty Of Pharmaceutical Sciences Toyama Medical And Pharmaceutical University
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波木 利志栄
Faculty Of Pharmaceutical Sciences Toyama Medical And Pharmaceutical University
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