Highly Asymmetric Diels-Alder Cycloaddition of Menthyl (Z)-(S)_S-3-(2-Pyridylsulfinyl)propenoate with Cyclohexa-1,3-diene

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概要

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• The Diels-Alder reaction of menthyl (Z)-(S)_S-3-(2-pyridylsulfinyl)propenoate with cyclohexa-1,3-diene in the presence of a Lewis acid, zinc bromide, afforded the endo cycloadduct in a highly diastereoselective manner in excellent yield. The absolute stereochemistry of the adduct was determined by transformation into (+)-bicyclo[2.2.2]oct-5-ene-2-endo-methanol with known absolute configuration.

• 社団法人日本薬学会の論文
• 1988-10-25

著者

• 小泉 徹

  富山医科薬科大学薬学部薬化学

• 小泉 徹

  Faculty Of Pharmaceutical Sciences Toyama Medical And Pharmaceutical University

• Koizumi T

  Faculty Of Pharmaceutical Sciences Toyama Medical And Pharmaceutical University

• 荒井 謙次

  Faculty of Pharmaceutical Sciences, Toyama Medical and Pharmaceutical University

• 高土居 雅法

  Faculty of Pharmaceutical Sciences, Toyama Medical and Pharmaceutical University

• 小泉 徹

  Department Of Synthetic Organic Chemistry:faculty Of Pharmaceutical Sciences Toyama Medical And Phar

• Koizumi Toru

  Faculty Of Pharmaceutical Sciences Toyama Medical And Pharmaceutical University

• 荒井 謙次

  Faculty Of Pharmaceutical Sciences Toyama Medical And Pharmaceutical University

• 高土居 雅法

  Faculty Of Pharmaceutical Sciences Toyama Medical And Pharmaceutical University

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