New Methods and Reagents in Organic Synthesis. 60. A New Synthesis of Aromatic and Heteroaromatic Amines Using Diphenyl Phosphorazidate (DPPA)
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概要
- 論文の詳細を見る
Aromatic and heteroaromatic organometallics (Grignard and Iithium compounds) react with diphenyl phosphorazidate (DPPA) to give labile phosphinyltriazenes. A study of the conversion of phosphinyltriazenes into amines has revealed that reductive work-up with aluminum hydride gives much better results than acidic or alkaline work-up. Sequential treatment of aromatic and heteroaromatic organometallics with DPPA, followed by aluminum hydride provides a convenient new method for the preparation of aromatic and heteroaromatic amines.
- 公益社団法人日本薬学会の論文
- 1986-04-25
著者
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塩入 孝之
Faculty of Pharmaceutical Sciences, Nagoya City University
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塩入 孝之
名城大学薬学部
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塩入 孝之
Faculty Of Pharmaceutical Sciences Nagoya City University
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青山 豊彦
Faculty of Pharmaceutical Sciences, Nagoya City University
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青山 豊彦
名古屋市立大学大学院薬学研究科
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森 繁広
Faculty of Pharmaceutical Sciences, Nagoya City University
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森 繁広
Faculty Of Pharmaceutical Sciences Nagoya City University
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青山 豊彦
Faculty Of Pharmaceutical Sciences Nagoya City University
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