Bicyclo [3. 3. 1] nonanes as Synthetic Intermediates. III. The Baeyer-Villiger Oxidation of Some Bicycloalkyl Phenyl Ketones
スポンサーリンク
概要
- 論文の詳細を見る
The Baeyer-Villiger oxidation of 3β-benzoylbicyclo [3. 3. 1] nonane (1), 8β-benzoylbicyclo [4. 3. 1] decane (2), and 3β-benzoylbicyclo [3. 2. 1] octane (3) is described. The ratio of the main product bicycloalkyl benzoate to its isomeric product phenyl bicycloalkanecarboxylate was determined to be ca. 10 : 1 by the ^1H-NMR measurement of the crude mixture. The Baeyer-Villiger reaction of cyclohexyl phenyl ketone (11) was also carried out and was found to give a similar result in its isomer ratio of the products. The high selectivity in this oxidation enabled the practicable preparation of bicyclo [3. n. 1] alkan-3-ones via bicyclo [3. n. 1] alk-3β-yl phenyl ketones to be achieved.
- 社団法人日本薬学会の論文
- 1978-08-25
著者
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村岡 修
Faculty of Pharmaceutical Sciences, Kinki University
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村岡 修
Faculty Of Pharmaceutical Sciences Kinki University
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百瀬 雄章
Faculty of Pharmaceutical Sciences, Kinki University
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百瀬 雄章
富山医薬大・薬
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百瀬 雄章
(present Address)faculty Of Pharmaceutical Sciences Toyama Medical And Pharmaceutical University
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百瀬 雄章
Faculty Of Pharmaceutical Sciences Osaka University
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百瀬 雄章
Faculty Of Pharmaceutical Sciences Kanazawa University
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Muraoka O
Shonai Regional Center For Plant Biotechnol. Yamagata
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