Chemical Reactivity of Oxidation Products of the Dithiolanylidenemalonate Fungicide, Isoprothiolane
スポンサーリンク
概要
- 論文の詳細を見る
Diisopropyl dithiolanylidenemalonate (isoprothiolane) was oxidized with m-chloroperbenzoic acid to give a monosulfoxide, disulfoxide, and disulfone. The monosulfoxide was subjected to addition reactions with such nucleophiles as methanol, thiols, and amines at the thioacetal carbon to open the dithiolane ring, affording a thiosulfinate, sulfinate and disulfide. The presence of a small amount of sodium carbonate accelerated the reactions and, moreover, reformed isoprothiolane from the ring-opened addition products. The further oxidation products were transformed into dithianes by reacting with nucleophiles. Isoprothiolane monosulfoxide inhibited alcohol dehydrogenase, an SH enzyme.
- 社団法人日本農芸化学会の論文
- 1993-02-23
著者
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SHIOTSUKI Takahiro
Department of Insect Physiology and Behavior, National Institute of Sericultural and Entomological S
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KUWANO Eiichi
Department of Agricultural Chemistry, Kyushu University
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ETO Morifusa
Department of Agricultural Chemistry, Kyushu University
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IKEDA Yukari
Department of Medical Science and Technology, School of Medicine, Kyushu University
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Eto Morifusa
Department Of Agricultural Chemistry Kyushu University
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Ikeda Yukari
Department Of Agricultural Chemistry Kyushu University
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Kuwano Eiichi
Department Of Agricultural Chemistry Faculty Of Agriculture Kyushu University
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Shiotsuki T
National Inst. Of Agrobiological Sci. Ibaraki Jpn
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Shiotsuki Takahiro
Laboratory Of Insect Growth Regulation Developmental Biology Department National Institute Of Agrobi
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Shiotsuki Takahiro
Department Of Insect Physiology And Behavior National Institute Of Sericultural And Entomological Sc
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Kuwano E
Kyushu Univ. Fukuoka Jpn
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Ikeda Yukari
Fac. Of Pharmaceutical Sciences Hokuriku Univ.
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Ishibashi Fumito
Department of Agricultural Chemistry, Faculty of Agriculture, Kyushu University
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Ishibashi F
Nagasaki Univ. Nagasaki Jpn
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Ishibashi Fumito
Department Of Agricultural Chemistry Faculty Of Agriculture Kyushu University
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Eto Morifusa
Department Of Agricultural Chemistry Faculty Of Agriculture Kyushu University
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