Stereochemistry and Reactions of Aziridinylphosphinothionates Derived from Amino Acids
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概要
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Aziridinylphosphinothionates were prepared from optically active ethyl hydrogen phenylphosphonothionates and 1-bromo-2-alkanamines derived from leucine or valine. The aziridine ring was opened by the action of some nucleophiles. Refluxing the aziridinylphosphinothionates in acetone with sodium iodide caused hydrolysis accompanied by the rearrangement of the sulfur atom to give β-mercaptoethylphosphonamidates. The reaction mechanism was discussed with stereochemical considerations. The insecticidal activity of the products was also examined.
- 社団法人 日本農芸化学会の論文
著者
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HIRASHIMA Akinori
Department of Agricultural Chemistry, Kyushu University
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Hirashima Akinori
Department Of Agricultural Chemistry Kyushu University
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Eto Morifusa
Department Of Agricultural Chemistry Faculty Of Agriculture Kyushu University
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