Synthesis of Optically Active 1,3,2-Oxazaphospholidine 2-Sulfides and 1,3,2-Benzodioxaphosphorin 2-Sulfides(Organic Chemistry)

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概要

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• The optical isomers of ten kinds of insecticidal 1,3,2-oxazaphospholidine 2-sulfides (OS) and two kinds of 1,3,2-benzodioxaphosphorin 2-sulfides (BS), including the commercial insecticide salithion, were synthesized in high optical purity by using two optically active aryl methyl phosphorochloridothionates (AMPC) as chiral two-step phosphorylating reagents. Their configurations were assigned according to the reaction mechanisms and supported by proton NMR information.

• 社団法人日本農芸化学会の論文
• 1987-02-23

著者

• KUWANO Eiichi

  Department of Agricultural Chemistry, Kyushu University

• ETO Morifusa

  Department of Agricultural Chemistry, Kyushu University

• HIRASHIMA Akinori

  Department of Agricultural Chemistry, Kyushu University

• Wu S‐y

  Laboratory Of Pesticide Chemistry Faculty Of Agriculture Kyushu University

• Wu Shao-yong

  Department Of Agricultural Chemistry Kyusyu University

• Kuwano Eiichi

  Department Of Agricultural Chemistry Faculty Of Agriculture Kyushu University

• Kuwano E

  Kyushu Univ. Fukuoka Jpn

• Eto Morifusa

  Department Of Agricultural Chemistry Kyushu University:(present Address)miyakonojo National College

• Hirashima A

  Department Of Applied Genetics And Pest Management Faculty Of Agriculture Graduate School Kyushu Uni

• Hirashima Akinori

  Department Of Agricultural Chemistry Kyushu University

• Eto Morifusa

  Department Of Agricultural Chemistry Faculty Of Agriculture Kyushu University

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