Chromano-analogs of Insecticidal Neolignans of the 1,4-Benzodioxane Type
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概要
- 論文の詳細を見る
Two haedoxan-analogs, (±)-(1S^*, 2R^*, 5R^*, 6S^*)-2-(2,6-dimethoxyphenoxy)-1-hydroxy-6-[(±)-(2S^*, 3R^*)-7/6-methoxy-3/2-methoxymethyl-2/3-(3,4-methylenedioxyphenyl)-3,4-dihydro-2H-chromen-6/7-yl]-3, 7-dioxabicyclo[3.3.0]octanes, were synthesized. They both had chromanyl groups instead of the (2R,3R)-6-methoxy-2-methoxymethyl-3-(3,4-methylenedioxyphenyl)-1,4-benzodioxan-7-yl group of the haedoxan molecule. In the synthesis, a (±)-(1S^*,2R^*,5R^*,6R^*)-isomer was obtained. An assay of these chromans indicated that the 1-oxygen atom of the 1,4-benzodioxane ring of haedoxans significantly contributed to their insecticidal activity.
- 社団法人日本農芸化学会の論文
- 1993-06-23
著者
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TANIGUCHI EIJI
Department of Surgery, Osaka Central Hospital
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YAMAUCHI Satoshi
Department of Internal Medicine (II) , KANSAI MEDICAL UNIVERSITY
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Yamauchi S
Faculty Of Agriculture Ehime University
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Yamauchi Satoshi
Laboratory Of Pesticide Chemistry Faculty Of Agriculture Kyushu University
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Gotanda Hiroshi
Department of Agricultural Chemistry, Faculty of Agriculture, Kyushu University
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Ishibashi Fumito
Department of Agricultural Chemistry, Faculty of Agriculture, Kyushu University
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Ishibashi F
Nagasaki Univ. Nagasaki Jpn
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Ishibashi Fumito
Department Of Agricultural Chemistry Faculty Of Agriculture Kyushu University
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Taniguchi Eiji
Department Of Agricultural Chemistry Faculty Of Agriculture Kyushu University
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Gotanda Hiroshi
Laboratory Of Pesticide Chemistry Faculty Of Agriculture Kyushu University
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Yamauchi Satoshi
Department Of Agricultural Chemistry Faculty Of Agriculture Kyushu University
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