Syntheses of (±)-Phrymarolin II and Its Stereoisomers(Organic Chemistry)
スポンサーリンク
概要
- 論文の詳細を見る
Phrymarolin II, a unique naturally-occurring lignan having a 1,2-dioxygenated 3,7-dioxabicyclo[3.3.0]octane skeleton, was synthesized by the reaction of sesamol, in the presence of cadmium carbonate, with 1-acetoxy-2-chloro-6-(2'-methoxy-4',5'-methylenedioxyphenyl)-3,7-dioxabicyclo[3.3.0]octane. The latter was prepared through 13 steps starting from an aldol condensation of β-vinyl-ν-butryolactone with 2-methoxy-4,5-methylenedioxybenzaldehyde. Three diastereomers of phrymarolin II were also obtained.
- 社団法人日本農芸化学会の論文
- 1986-12-23
著者
-
TANIGUCHI EIJI
Department of Surgery, Osaka Central Hospital
-
Taniguchi E
Department Of Agricultural Chemistry Faculty Of Agriculture Kyushu University
-
Ishibashi Fumito
Department of Agricultural Chemistry, Faculty of Agriculture, Kyushu University
-
Ishibashi Fumito
Department Of Agricultural Chemistry Faculty Of Agriculture Kyushu University
-
Taniguchi Eiji
Department Of Agricultural Chemistry Faculty Of Agriculture Kyushu University
関連論文
- Totally Laparoscopic Distal Gastrectomy Using the Hand-Sewn Billroth-I Anastomotic Technique : Report of a Case
- Myelodysplastic Syndrome Following Therapy for Brain Tumor
- Laparoscopic Surgery for Blind Pouch Syndrome Following Roux-en Y Gastrojejunostomy: Report of Case
- Solitary Brain Metastasis From Renal Cell Carcinoma 15 Years After Nephrectomy
- Reconstruction of Pterional Key Hole Using Three-dimensional Titanium Plate : Technical Note
- A Case of Venous Angioma with Arteriovenous Shunts : Case Report
- B309 フェロモン分泌阻害剤の pharmacophore モデリング
- Completely Laparoscopic Total Colectomy for Chronic Constipation : Report of a Case
- Laparoscopic-Assisted Surgery for Crohn's Disease : Reduced Surgical Stress Following Ileocolectomy
- Syntheses of Arylisoxazolylphenylacetic Acids and Arylisoquinolinones and Their Plant Growth-regulating Activities(Pesticide Chemistry)
- Syntheses and Plant Growth-regulating Activity of 2-Substituted Phenylacetic Acid Derivatives(Pesticide Chemistry)
- A New Parameter for Assessing Postoperative Recovery of Physical Activity Using an Accelerometer
- Laparoscopic Left-Sided Nissen Fundoplication in Children
- Sesquilignan Haedoxans : Interaction with the GABA_A Receptor in Rat Brain
- Synthesis and Octopaminergic-agonist Activity of 3-(Substituted Phenyl) imidazolidine-2-thiones and Related Compounds
- Effect on Insecticidal Activity of Substituents at the 1,4-Benzodioxanyl Moiety of Haedoxan
- Syntheses of 2-Substituted 6/7-Methoxy-1,4-benzodioxan-7/6-carbaldehydes
- Enantioselective Synthesis of a (+)-(2R, 3R)-1,4-Benzodioxane-7-carbaldehyde Derivative, a Key Intermediate in the Total Synthesis of Haedoxan Analogs
- Chromano-analogs of Insecticidal Neolignans of the 1,4-Benzodioxane Type
- Chemical Reactivity of Oxidation Products of the Dithiolanylidenemalonate Fungicide, Isoprothiolane
- Insecticidal Activity of Sesquilignans with a 3-Aryl-6-methoxy-2-methoxymethyl-1,4-benzodioxanyl Group
- Synthesis of the Benzodioxane Portion of Haedoxans(Organic Chemistry)
- PC22 SYNTHESES, ABSOLUTE CONFIGURATIONS AND INSECTICIDAL ACTIVITIES OF BOTH ENANTIOMERS OF HAEDOXAN D
- Syntheses of (±)-Phrymarolin II and Its Stereoisomers(Organic Chemistry)
- Structure of the Novel Insecticidal Sesquilignan, Haedoxan A(Organic Chemistry)
- Influence on Insecticidal Activity of the 3-(3,4-Methylenedioxyphenyl) Group in the 1,4-Benzodioxanyl Moiety of Haedoxan
- Synthesis and Insecticidal Activity of Lignan Analogs (II)
- Synthesis and Insecticidal Activity of Sesquilignan Analogs with 2-Alkyl-6-methoxy-3-(3,4-methylenedioxyphenyl)-1,4-benzodioxanyl Group
- Synthesis and Insecticidal Activity of Lignan Analogs (1)(Pesticide Chemistry)
- Synthesis and Insecticidal Activity of Lignan Analogs (III)
- Syntheses of (±)-Haedoxan A, D, E and Their Stereoisomers(Organic Chemistry)
- Synthesis and absolute configuration of the acetalic lignan (+)-phrymarolin I.